An In-situ Method for Assessing the Kinetics of Acid Attack on Iron-richAlkali-activated Materials

Abstract

In iron-rich alkali-activated materials (AAMs), iron is present in both the ferrous and ferric states. Fe3+ is considered to be present in a silicate network and the dissolution of Fe3+ under acid attack can be taken as an indication of the deterioration of the AAMs framework. Conventional methods for evaluating the acid resistance of AAMs are based on the durability standards for OPC concrete with indicators such as mass change and dimensional change, or by measuring the corroded depth. All of these methods are measured based on solid samples and many samples have to be prepared to obtain different points in a time profile. Here we propose nuclear magnetic resonance (NMR) relaxometry measurements as an in-situ method for the direct determination of dissolution kinetics of Fe3+ ions in an acid solution with high temporal resolution. The leaching kinetics of iron-rich AAMs in (sulfuric) acid can be described by the Real Physical Picture (RPP) kinetic model, which was originally used to describe the gas-solid interaction. The fitting results show that the leaching process is controlled by chemical reactions at the beginning and by diffusion over time.

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