Tuning the incompatibility between recycled plastic aggregates and cement matrix with polymer-nano silica hybrids

                                
==Abstract==

Use of recycled waste plastics as the aggregates in construction materials has attracted increasingly gained attention for sustainable construction industry with great environmental benefits. However, the soft plastics and rigid cement matrix can naturally induce the great aggregate-matrix incompatibility, which results in the degradation of engineering properties of cement-based materials containing recycled plastic aggregates (RPAs). To overcome this shortage, this work reports a strategy of tuning the cement matrix with polymer-nano silica (P-nS) hybrids. Ethylene vinyl acetate (EVA) and recycled polypropylene (PP) were selected as the coating polymer and RPA, respectively. Density, strength, water sorptivity and carbonation resistance were measured to assess the physical and mechanical properties of the mortars with recycled PP particles. Microstructure was analyzed using scanning electron microscopy (SEM) with backscattered electron (BSE) and energy-dispersive X-ray spectroscopy (EDS). Results showed that the addition of P-nS hybrids into cement decreases density, mitigates strength reduction, obstructs water sorption, but have positive and negative effects on carbonation resistance of the cement mortars with RPA. The P-nS hybrids build the organic–organic links between the cement matrix and RPA, and coordinate their deformations. The findings of this work proof the proposed strategy of tuning the compatibility between soft aggregates and rigid matrix with the engineered microstructure towards enhancing the recyclability of waste plastics in construction materials.